Secondly, the potential of aluminum (Al) batteries as rechargeable energy storage is underscored by their notable volumetric capacity attributed to its high density (2.7 g cm −3 at 25 °C) and its capacity to exchange three electrons, surpasses that of Li, Na, K, Mg, Ca, and Zn.
In some instances, the entire battery system is colloquially referred to as an “aluminum battery,” even when aluminum is not directly involved in the charge transfer process. For example, Zhang and colleagues introduced a dual-ion battery that featured an aluminum anode and a graphite cathode.
Research on corrosion in Al-air batteries has broader implications for lithium-ion batteries (LIBs) with aluminum components. The study of electropositive metals as anodes in rechargeable batteries has seen a recent resurgence and is driven by the increasing demand for batteries that offer high energy density and cost-effectiveness.
One unique advantage of Al S batteries, compared to aluminum-air (Al-air) batteries, is their closed thermodynamic system. Additionally, Al S batteries have a notable edge over AIBs because the cathode material in Al S batteries doesn't rely on intercalation redox processes.
4. Aluminum-air batteries have a distinct advantage in their ability to operate efficiently in aqueous environments, primarily due to their wide operating voltage range. However, this beneficial voltage range is typically achieved when using alkaline electrolytes.
Aluminum's manageable reactivity, lightweight nature, and cost-effectiveness make it a strong contender for battery applications. Practical implementation of aluminum batteries faces significant challenges that require further exploration and development.
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